We seem to write a lot about electric cars, as well as a little bit about hydrogen, but those aren't the only potential planet friendly fuel sources out there.
There are synthetic 'eFuels', something that Porsche has been championing and investing heavily in, and that Formula 1 is putting at the centre of their strategy to be carbon-neutral in the next few years. Then there are also biofuels, some of which are more promising and more sustainable than others, palm oil diesel for example is probably not the best way to go.
What about transforming sugar into the kind of hydrocarbons found in fossil fuel based auto fuels though?
It might sound a bit like alchemy, the equivalent of lead into gold for the climate-crisis age, but it's actually a reality that scientists at the University of Buffalo and the University of California, Berkely, have been researching.
In a study in Nature Chemistry, researchers, led by biochemists Zhen Q. Wang and Michelle C. Y. Chang, report harnessing the wonders of biology and chemistry to turn glucose (a type of sugar) into olefins (a type of hydrocarbon, and one of several types of molecules that make up gasoline).
The paper, published on Nov. 22, marks an advance in efforts to create sustainable biofuels.
Olefins comprise a small percentage of the molecules in gasoline as it’s currently produced, but the process the team developed could likely be adjusted in the future to generate other types of hydrocarbons as well, including some of the other components of gasoline, Wang says. She also notes that olefins have non-fuel applications, as they are used in industrial lubricants and as precursors for making plastics.
A two-step process using sugar-eating microbes and a catalyst
To complete the study, the researchers began by feeding glucose to strains of E. coli that don’t pose a danger to human health.
“These microbes are sugar junkies, even worse than our kids,” Wang jokes.
The E. coli in the experiments were genetically engineered to produce a suite of four enzymes that convert glucose into compounds called 3-hydroxy fatty acids. As the bacteria consumed the glucose, they also started to make the fatty acids.
To complete the transformation, the team used a catalyst called niobium pentoxide (Nb2O5) to chop off unwanted parts of the fatty acids in a chemical process, generating the final product: the olefins.
The scientists identified the enzymes and catalyst through trial and error, testing different molecules with properties that lent themselves to the tasks at hand.
“We combined what biology can do the best with what chemistry can do the best, and we put them together to create this two-step process,” says Wang. “Using this method, we were able to make olefins directly from glucose.”
Glucose comes from photosynthesis, which pulls CO2 out of the air
“Making biofuels from renewable resources like glucose has great potential to advance green energy technology,” Wang says.
“Glucose is produced by plants through photosynthesis, which turns carbon dioxide (CO2) and water into oxygen and sugar. So the carbon in the glucose — and later the olefins — is actually from carbon dioxide that has been pulled out of the atmosphere,” Wang explains.
More research is needed, however, to understand the benefits of the new method and whether it can be scaled up efficiently for making biofuels or for other purposes. One of the first questions that will need to be answered is how much energy the process of producing the olefins consumes; if the energy cost is too high, the technology would need to be optimized to be practical on an industrial scale.
Scientists are also interested in increasing the yield. Currently, it takes 100 glucose molecules to produce about 8 olefin molecules, Wang says. She would like to improve that ratio, with a focus on coaxing the E. coli to produce more of the 3-hydroxy fatty acids for every gram of glucose consumed.
